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Citriodiol and Citrepel are trade names for the compound that is derived from Lemon Eucalyptus Oil and used as the active ingredient in several different insect repellents.
Citronella Oil has been used as a natural insect repellent for thousands of years. It's an essential oil obtained from the leaves and stems of a type of grass originating in tropical Asia.
Thiamine (Vitamin B1) is said to have insect repellent properties if taken in large doses and it can be usual for it to be absorbed through the skin.